Hydrogen can be stored in caverns that are hermetically sealed against the medium. Wellheads are used at the interface between aboveground plant facilities and underground storage, Hartmann Valves explains. In addition to wellheads, ball valves are used for pipelines and compressor stations.Avoiding explosive concentration
Also the Waldemar Pruss Armaturenfabrik fully focuses on dealing with the challenges connected to hydrogen valves. A particular risk for highly loaded pressure-bearing components is ‘hydrogen embrittlement’; a material fatigue caused by the penetration of hydrogen into the metal lattice, which leads to the formation of cracks. The company emphasises that this is “a risk to be taken seriously”. Hydrogen is also the chemical element with the lowest density and diffuses comparatively easily through materials. Pruss says that “this requires special solutions for spindle and housing seals”.
Pruss advises particular caution because hydrogen is both odourless and tasteless and, depending on the concentration, can react explosively with the ambient air. “When selecting materials, we therefore take great care to check their suitability for use in terms of hardness values, explosive decompression and ductility”, the company explains.Round sealing seats
In order to enable absolute tightness, müller quadax works with the 4-fold eccentric construction principle for its valves. The butterfly valves have a round sealing seat with a uniform wall thickness all around. “The design differs significantly from the common triple eccentric designs which have an elliptical sealing seat”, the company explains. Material expansions have a homogeneous effect on the entire sealing surface due to high temperature fluctuations “and thus ensure optimum sealing tightness”, the company continues. In addition, the Quadax® H2 valve is equipped with a special sealing ring made of a dedicated material that “functions perfectly even at these extremely low temperatures”.Safety valves for hydrogen filling stations
Goetze KG supplies high-pressure safety valves for electrolyser manufacturers as well as safety valves for hydrogen filling stations – because in addition to the energy grid and industry, focus is also on mobility. Goetze sees an increasing international demand for hydrogen technology and supplies safety valves with up to 1000 bar to Chinese and Spanish plant manufacturers. China is already putting a particular emphasis on this and the world’s largest hydrogen filling station was built in Beijing last year. “Eight hydrogen fuel pumps are ready to refuel up to 600 vehicles on a daily basis”, Goetze reports. This is possible thanks to the large volume of up to five tonnes production capacity, embedded in a 200,000 square metre hydrogen park.Demanding technical challenges
The technical requirements for hydrogen filling stations are higher than for conventional ones, emphasises Herose: At these stations, the gas is stored in low-pressure storage tanks at about 20 bar. In car fuel tanks, however, the hydrogen must be compressed considerably more because of the necessary energy density. “Compressors first compress the gas to 1000 bar and then store it temporarily in high-pressure tanks. To prevent the gas from heating up too much during refuelling, it passes through a pre-cooler”, the company explains. The refuelling process is controlled electronically, and the pressure in the tank is regulated at 700 bar. “If the pressure drops unexpectedly, the safety valve opens and allows the excess pressure to escape unhindered into the atmosphere.” As hydrogen is thirteen times lighter than air, it escapes upwards and is not dangerous. Valves with highest safety standards are required for the passage from petrol station storage tanks to car fuel tanks.
And how might hydrogen use look in the future? In Fraunhofer IFF’s view, “systemically integrated hydrogen production” is a valuable concept. Not only the hydrogen produced during electrolysis would be used, but also oxygen; i.e. for welding processes or for ozonation of sewage treatment plants. “Problematic micropollutants such as pharmaceuticals, pesticides or cosmetics can be removed from wastewater by adding ozone”, Fraunhofer IFF explains. Another possible use is in agriculture, where the oxygen could be used for desulphurisation of biogas plants. These are more uses that show further, promising prospects.
Innovationen rund um Industriearmaturen und Ventile sind auf der VALVE WORLD EXPO vom 29.11. bis 1.12. 2022 in den Hallen 1 und 3 des Düsseldorfer Messegeländes zu sehen. Aktuelle Branchen- und Produktinformationen befinden sich im Internetportal unter www.valveworldexpo.de